Molecular assembly of amino acid interlinked, topologically symmetric, π-complementary donor–acceptor–donor triads

نویسندگان

  • M B Avinash
  • K V Sandeepa
  • T Govindaraju
چکیده

Amino acid interlinked pyrene and naphthalenediimide (NDI) based novel donor-acceptor-donor (D-A-D) triads are designed to exploit their topological symmetry and complementary π-character for facile charge-transfer complexation. Consequently, free-floating high-aspect-ratio supercoiled nanofibres and hierarchical helical bundles of triads are realized by modulating the chemical functionality of interlinking amino acids.

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عنوان ژورنال:

دوره 9  شماره 

صفحات  -

تاریخ انتشار 2013